Voltammetry at 1,6-Dichlorohexane | Water Interface.

Electrochemical study of the assisted transfer of silver ion by 1,5-cyclooctadiene at the 1,6-dichlorohexane/water interface.

The transfer of Ag+ ion across a polarized 1,6-dichlorohexane/water interface assisted by an alkene or olefin ligand, 1,5-cyclooctadiene (COD), was studied by cyclic voltammetry. Even if COD was absent from the organic phase, Ag+ ion gave a reversible voltammetric wave, and the formal potential of the non-assisted ion-transfer at the 1,6-dichlorohexane/water interface was determined from the re...

Ion-transfer voltammetry at a polarized room-temperature molten salt/water interface.

Tetraoctylammonium cation forms a room-temperature molten salt (RTMS) with 2,4,6-trinitrophenolate anion. The RTMS is immiscible with water (W) and forms a stable RTMS/W interface. It has been shown that the RTMS/W interface can be electrochemically polarized. A well-defined voltammetric wave due to the transfer of thiocyanate ion across the RTMS/W interface was observed within the potential wi...

Organic ions at the air/water interface

Direct spectroscopic evidence of the presence of organic phenolate ions at the air/aqueous interface has been established using the nonlinear spectroscopic technique of vibrational sum frequency generation (SFG). By probing the phenol C–OH and the phenolate C–O vibrational stretches, which occur in the range of 1200–1300 cm and are distinguishable, we have succeeded in determining the identitie...

Hydrated electrons at the water/air interface.

The dynamics of hydrated electrons at the water/air interface are investigated using time-resolved second-harmonic generation spectroscopy. Initial solvation occurs in approximately 1 ps, and the electron remains at the interface for >750 ps. The location of the electron relative to the dividing surface is investigated using surfactants, which show that the electron is hydrated in the interfaci...

Connectivity at the Land-Water Interface